Studies on biodegradable polyurethane-SWCNTs nanocomposite films by covalent approach: Physicochemical, electric and mechanical properties

• Published in: Applied surface science Vol. 449; pp. 745 - 754
• Main Authors: Gurusamy Thangavelu, Senthil A., Murali, Adhigan, Sharanya, Madhurakkod, Jaisankar, Sellamuthu N., Mandal, Asit Baran
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 15-08-2018
• Subjects: Biodegradable nanocomposite films; Covalent approach; Functionalized carbon nanotubes; Impedance measurement; Tensile strength; Thermal stability; Impedance measurement; Functionalized carbon nanotubes; Covalent approach; Thermal stability; Tensile strength; Biodegradable nanocomposite films
• ISSN: 0169-4332; 1873-5584
• DOI: 10.1016/j.apsusc.2018.01.275

•Covalent strategy is executed to enhance the properties of polyurethane films using hydroxyl single-walled carbon nanotubes by a viable approach.•Established an efficient and mild synthetic route to convert pristine-SWCNTs into hydroxyl-SWCNTs in good yield.•PU-SWCNTs nanocomposite films, uniformly distributed with SWCNTs revealed reinforcement in conductivity, thermal and mechanical properties.
Biodegradable control polyurethane (PU) film as well as PU nanocomposite films (PU-SWCNTs), covalently incorporated with minor amount of hydroxyl single walled carbon nanotubes [(OH)n-SWCNTs] have been formulated to investigate the influence of SWCNTs on the matrix of PU (3-dimensional network of soft and hard segments). Biodegradable polyol, polycaprolactone triol (PCL, ∼70%), diisocyanate (TDI, ∼21%) and 1, 4- butane diol (BDO) as chain extender were taken to react at 70 °C under inert atmosphere in the presence of amine catalyst (PMDETA) via prepolymer process to obtain the control PU film by casting approach, whereas in situ addition of (OH)n-SWCNTs into the above formulation can afford the covalently incorporated PU-SWCNTs films by the identical protocol. PU and PU-SWCNTs films loaded with variable quantity of (OH)n-SWCNTs (0.01, 0.03, 0.05, 0.1 and 0.3 wt.%) were characterized to identify the enhancement of their physicochemical properties such as optical, electrical conductivity, thermal and mechanical properties. These film samples were characterized by FT-IR, Raman, ATR-FT IR, UV–vis DRS, solid state 13C NMR, XRD, impedance measurements, DSC, TGA, EDX, SEM, AFM, optical microscope and tensile strength data.