Propyl phthalimide-modified thiacalixphenyl[4]arene as a “turn on” chemosensor for Hg(II) ions

• Published in: Journal of luminescence Vol. 179; pp. 378 - 383
• Main Authors: Modi, Krunal, Panchal, Urvi, Mehta, Viren, Panchal, Manthan, Kongor, Anita, Jain, V.K.
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01-11-2016
• Subjects: Binding behavior; Mercury; Spectrofluorimetry; Thiacalixphenylarene; Thiacalixphenylarene; Binding behavior; Spectrofluorimetry; Mercury
• ISSN: 0022-2313; 1872-7883
• DOI: 10.1016/j.jlumin.2016.07.019

Thiacalixphenyl[4]arene tetra N-(3-propyl) phthalimide (TPTN3PPh), a novel thiacalixarene bearing a N-(3-bromopropyl) phthalimide group, was synthesized and characterized by Electrospray Ionization Mass Spectrometry (ESI-MS) and NMR. The ability of TPTN3PPh to recognize the cations Fe(III), Cu(II), Cd(II), Zn(II), Cr(II), Ca(II), Co(II), Mg(II), Ag(I), Pb(II), Sr(II), Hg (II), Th(II), Ba(II), Bi(II), K(I), and Na(I) was evaluated. Only Hg(II) was selectively and sensitively detected using a spectrofluorimetric method, with a detection limit as low as 3.10×10−9M. Analysis of the binding behavior of TPTN3PPh with Hg(II) revealed 1:2 complex formation. Real sample analysis detected nano levels of mercury ions in a waste water samples.