Microimpedance—Localized material analysis

Many technically relevant materials are non-homogeneous in structure. Their investigation requires a locally resolved surface analysis. An exact determination of the accessed area and a potentiostatic control in a three-electrode configuration are necessary. This becomes possible by capillary-based...

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Bibliographic Details
Published in:Electrochimica acta Vol. 51; no. 8; pp. 1431 - 1436
Main Authors: Lohrengel, M.M., Heiroth, S., Kluger, K., Pilaski, M., Walther, B.
Format: Journal Article Conference Proceeding
Language:English
Published: Oxford Elsevier Ltd 20-01-2006
Elsevier
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Summary:Many technically relevant materials are non-homogeneous in structure. Their investigation requires a locally resolved surface analysis. An exact determination of the accessed area and a potentiostatic control in a three-electrode configuration are necessary. This becomes possible by capillary-based microcells which enable local impedance measurements and even impedance mapping of the surface. Different aspects and strategies of this microimpedance spectroscopy are presented and discussed, together with some examples.
ISSN:0013-4686
1873-3859
DOI:10.1016/j.electacta.2005.02.120