The effect of CO2 on the viscosity of polystyrene/limonene solutions

• Published in: The Journal of supercritical fluids Vol. 88; pp. 26 - 37
• Main Authors: Gutiérrez, C., Garcia, M.T., Curia, S., Howdle, S.M., Rodriguez, J.F.
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01-04-2014
• Subjects: Carbon dioxide; Limonene; Phase separation; Polystyrene; Rheology; Viscosity; Viscosity; Limonene; Polystyrene; Rheology; Phase separation; Carbon dioxide
• ISSN: 0896-8446; 1872-8162
• DOI: 10.1016/j.supflu.2014.01.012

•Effect of pressure, temperature and polymer concentration was studied on the viscosity of PS/limonene solutions.•Arrhenius-type equation was used to fit the effect of pressure and temperature.•The viscosity can be used to predict the critical mixing pressure.
We demonstrate the use of a quartz crystal viscometer to determine the viscosity of solutions of polystyrene in limonene in the presence of high pressure carbon dioxide. These measurements were determined up to 50bar in the range of temperature from 20 to 40°C and at 0.025, 0.05, 0.1, 0.2, 0.3 and 0.4g PS per ml of limonene. The selected variables of study (pressure, temperature and concentration) were statistically significant over the range of viscosity studied. The viscosities of the solutions at all loadings were found to decrease with increasing temperature and pressure while the plastising effect of CO2 prevailing over the hydrostatic pressure applied by the gas. The flow activation energies of the system were obtained from an Arrhenius fitting of the experimental data reaching a maximum of 40kJ/mol. An empirical model correlating the viscosity of the mixtures to pressure and temperature was developed in order to interpolate and extrapolate in the study region or in a range close to the working limits. Finally, the viscosity data were used to determine the solvent quality and to quantify the demixing points of the mixtures.