Non-Equilibrium Crystallization of Monotectic Zn-25%Bi Alloy under 600 g

• Published in: Materials Vol. 14; no. 15; p. 4341
• Main Authors: Boczkal, Grzegorz, Palka, Pawel, Kokosz, Piotr, Boczkal, Sonia, Mrowka-Nowotnik, Grazyna
• Format: Journal Article
• Language: English
• Published: Basel MDPI AG 03-08-2021; MDPI
• Subjects: Alloys; Bimetals; Bismuth base alloys; Chemical precipitation; Crystallization; Electric cells; Equilibrium; Experiments; Grain size; Microstructure; Phase transitions; Precipitates; Sedimentation & deposition; Separation; Supergravity; Zinc
• ISSN: 1996-1944; 1996-1944
• DOI: 10.3390/ma14154341

This study investigated the influence of supergravity on the segregation of components in the Zn–Bi monotectic system and consequently, the creation of an interface of the separation zone of both phases. The observation showed that near the separation boundary, in a very narrow area of the order of several hundred microns, all types of structures characteristic for the concentration range from 0 to 100% bismuth occurred. An additional effect of crystallization in high gravity is a high degree of structural order and an almost perfectly flat separation boundary. This is the case for both the zinc-rich zone and the bismuth-rich zone. Texture analysis revealed the existence of two privileged orientations in the zinc zone. Gravitational segregation also resulted in a strong rearrangement of the heavier bismuth to the outer end of the sample, leaving only very fine precipitates in the zinc region. For comparison, the results obtained for the crystallization under normal gravity are given. The effect of high orderliness of the structure was then absent. Despite segregation, a significant part of bismuth remained in the form of precipitates in the zinc matrix, and the separation border was shaped like a lens. The described method can be used for the production of massive bimaterials with a directed orientation of both components and a flat interface between them, such as thermo-generator elements or bimetallic electric cell parts, where the parameters (thickness) of the junction can be precisely defined at the manufacturing stage.