Vanadium catalyzed oxidation with hydrogen peroxide

In this short account reactivity, structural and mechanistic studies concerning the behaviour of peroxovanadates toward a number of different substrates are collected. Homogeneous and two-phase systems are presented. Furthermore, interesting synthetic results obtained with the use of ionic liquids a...

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Bibliographic Details
Published in:	Inorganica Chimica Acta Vol. 363; no. 9; pp. 1935 - 1946
Main Authors:	Conte, Valeria, Floris, Barbara
Format:	Journal Article
Language:	English
Published:	Elsevier B.V 10-06-2010
Subjects:	Hydrogen peroxide Ionic liquids Mechanisms Oxidation Vanadium Ionic liquids Mechanisms Oxidation Hydrogen peroxide Vanadium
Online Access:	Get full text
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Summary:	In this short account reactivity, structural and mechanistic studies concerning the behaviour of peroxovanadates toward a number of different substrates are collected. Homogeneous and two-phase systems are presented. Furthermore, interesting synthetic results obtained with the use of ionic liquids as reaction media are also presented. Vanadium peroxides are known as very effective oxidants of different organic and inorganic substrates. In this short account reactivity, structural and mechanistic studies concerning the behaviour of peroxovanadates toward a number of different substrates are collected. Homogeneous and two-phase systems are presented, in addition, interesting synthetic results obtained with the use of ionic liquids as reaction media are also presented.
ISSN:	0020-1693 1873-3255
DOI:	10.1016/j.ica.2009.06.056