Oligoether-strapped meso-pyrimidinylporphyrins

Oligoether-strapped meso-pyrimidinylporphyrins

Bis(oligoether-strapped) zinc(II)-meso-pyrimidinylporphyrins were readily synthesized via nucleophilic aromatic substitution reactions of biscathechol-substituted tri- or tetraethylene glycol straps on the upper and lower faces of a Zn(II)-A2B2-meso-dichloropyrimidinylporphyrin precursor. The crown...

Full description

Saved in:
Bibliographic Details
Published in:Tetrahedron letters Vol. 53; no. 19; pp. 2406 - 2409
Main Authors: Ngo, Thien H., Nitychoruk, Klaudia A., Lentz, Dieter, Rzymowski, Tomasz, Dehaen, Wim, Maes, Wouter
Format: Journal Article
Language:English
Published: Elsevier Ltd 09-05-2012
Subjects:
Bridges (structures)
Crown ethers
Dichloropyrimidines
Glycols
Holes
Nucleophilic aromatic substitution
Planes
Porphyrins
Precursors
Straps
Supramolecular receptors
Tetrahedrons
NMEJCSDOAZNGFL-AEZOJJEYSA-N
Nucleophilic aromatic substitution
VULVWBLGHLJUQQ-KCDFEJGJSA-N
Crown ethers
MRHGOAKYYORQGQ-UHFFFAOYSA-N
JNUYKSSAIRFGSZ-MCYPTXCVSA-N
NGMMLBQJKGLXDH-WEHNMEAWSA-N
DWODZPNTYFEBQJ-DPYHNODUSA-N
GYRCGPLUVWLQIO-AOVMHBBDSA-N
Supramolecular receptors
LMSFUWKGADQXES-UHFFFAOYSA-N
Dichloropyrimidines
XATAPWYLOXDSSI-UHFFFAOYSA-N
Porphyrins
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Bis(oligoether-strapped) zinc(II)-meso-pyrimidinylporphyrins were readily synthesized via nucleophilic aromatic substitution reactions of biscathechol-substituted tri- or tetraethylene glycol straps on the upper and lower faces of a Zn(II)-A2B2-meso-dichloropyrimidinylporphyrin precursor. The crown ether-like bridges surrounding the porphyrin core create peculiar cavities above and below the macrocyclic plane with appealing features for supramolecular host–guest chemistry.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:0040-4039
1873-3581
DOI:10.1016/j.tetlet.2012.02.116