An analysis of direct-injection spark-ignition (DISI) soot morphology

• Published in: Atmospheric environment (1994) Vol. 49; no. 1; pp. 268 - 274
• Main Authors: Barone, Teresa L., Storey, John M.E., Youngquist, Adam D., Szybist, James P.
• Format: Journal Article
• Language: English
• Published: United States Elsevier Ltd 01-03-2012
• Subjects: 02 PETROLEUM; AIR; Emissions; ENGINES; ETHANOL; GASOLINE; Gasoline exhaust; IMPINGEMENT; LUBRICATING OILS; MORPHOLOGY; Nanoparticles; PISTONS; SOOT; TRANSMISSION ELECTRON MICROSCOPY; Nanoparticles; Gasoline exhaust; Transmission electron microscopy; Morphology; Emissions
• ISSN: 1352-2310; 1873-2844
• DOI: 10.1016/j.atmosenv.2011.11.047

We have characterized particle emissions produced by a 4-cylinder, 2.0 L DISI engine using transmission electron microscopy (TEM) and image analysis. Analyses of soot morphology provide insight to particle formation mechanisms and strategies for prevention. Particle emissions generated by two fueling strategies were investigated, early injection and injection modified for low particle number concentration emissions. A blend of 20% ethanol and 80% emissions certification gasoline was used for the study given the likelihood of increased ethanol content in widely available fuel. In total, about 200 particles and 3000 primary soot spherules were individually measured. For the fuel injection strategy which produced low particle number concentration emissions, we found a prevalence of single solid sub-25nm particles and fractal-like aggregates. The modal diameter of single solid particles and aggregate primary particles was between 10 and 15nm. Solid particles as small as 6nm were present. Although nanoparticle aggregates had fractal-like morphology similar to diesel soot, the average primary particle diameter per aggregate had a much wider range that spanned from 7 to 60nm. For the early fuel injection strategy, liquid droplets were prevalent, and the modal average primary particle diameter was between 20 and 25nm. The presence of liquid droplets may have been the result of unburned fuel and/or lubricating oil originating from fuel impingement on the piston or cylinder wall; the larger modal aggregate primary particle diameter suggests greater fuel-rich zones in-cylinder than for the low particle number concentration point. However, both conditions produced aggregates with a wide range of primary particle diameters, which indicates heterogeneous fuel and air mixing.
► We characterized direct-injection spark-ignition soot morphology. ► We analyzed solid sub-25nm spheres and aggregate primary particle sizes. ► The most abundant single solid spheres were 10–15nm diameter. ► Aggregate primary particle diameters ranged from 7 to 60nm.