Electrochemical phosphorylation of arenes catalyzed by cobalt under oxidative and reductive conditions

Electrochemical phosphorylation of arenes catalyzed by cobalt under oxidative and reductive conditions

Catalyst capable to operate in cathode and anode spaces simultaneously was found. Electrochemical regeneration of active form of catalyst Co 2+ bpy (1%) under oxidative as well as reductive conditions allows the C-H/P-H coupling of dialkyl-H-phosphonate and various aromatic or heteroaromatic compoun...

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Bibliographic Details
Published in:Phosphorus, sulfur, and silicon and the related elements Vol. 194; no. 4-6; pp. 506 - 509
Main Authors: Strekalova, S. O., Grinenko, V. V., Gryaznova, T. V., Kononov, A. I., Dolengovski, E. L., Budnikova, Y. H.
Format: Journal Article
Language:English
Published: Abingdon Taylor & Francis 27-05-2019
Taylor & Francis Ltd
Subjects:
Aromatic compounds
Catalysis
Catalysts
CH-substitution
cobalt
Coupling (molecular)
electrocatalysis
Heterocyclic compounds
Phosphonates
Phosphorylation
Regeneration
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Summary:Catalyst capable to operate in cathode and anode spaces simultaneously was found. Electrochemical regeneration of active form of catalyst Co 2+ bpy (1%) under oxidative as well as reductive conditions allows the C-H/P-H coupling of dialkyl-H-phosphonate and various aromatic or heteroaromatic compounds.
ISSN:1042-6507
1563-5325
DOI:10.1080/10426507.2018.1540488