Lithium Extraction Techniques and the Application Potential of Different Sorbents for Lithium Recovery from Brines

• Published in: Mineral processing and extractive metallurgy review Vol. 44; no. 4; pp. 261 - 280
• Main Authors: Reich, Rebekka, Slunitschek, Klemens, Danisi, Rosa Micaela, Eiche, Elisabeth, Kolb, Jochen
• Format: Journal Article
• Language: English
• Published: Philadelphia Taylor & Francis 19-05-2023; Taylor & Francis Ltd
• Subjects: Aluminum; Aluminum hydroxide; Antimony; Aqueous solutions; Clay minerals; Degradability; direct lithium extraction (DLE); Evaluation; Evaporation; geothermal; Geothermal power; Geothermal power plants; High temperature fluids; inorganic sorbents; Ion exchange; Iron; Iron phosphates; Lithium; Lithium carbonate; Manganese; Manganese oxides; Minerals; Niobium; Niobium oxides; Power plants; Solvent extraction; Sorbents; Sorption; Tantalum; Tantalum oxides; Tin; Titanium oxide; Titanium oxides; Zeolites; Zirconium
• ISSN: 0882-7508; 1547-7401
• DOI: 10.1080/08827508.2022.2047041

Geothermal power plants produce large amounts of high-temperature fluids from variable depths. These fluids can be enriched in lithium to up to 240 mg/L, rendering them an exploitable resource, not yet processed at industrial scale. The pressure on Li demand is expected to increase in the future, making the technical degradability of new Li resources indispensable. We examine Li-extraction methods from aqueous solutions systematically, dealing with evaporation, direct precipitation, membrane-related processes, solvent extraction, sorption, and ion exchange. Sorption and ion-exchange techniques are regarded to be the most promising methods with a high potential for the feasible lithium extraction. Therefore, Li sorption on different inorganic sorbents, in particular for the implementation into operating geothermal power plants, is evaluated. Inorganic sorbents, such as lithium-manganese oxide, titanium oxide, aluminum hydroxide, iron phosphate, clay minerals, and zeolite group minerals besides other sorbents, e.g. zirconium phosphate, tin antimonate, antimony oxide, tantalum oxide, and niobium oxide, are regarded. Promising inorganic sorbents for an environmentally friendly, efficient, and selective Li extraction are lithium-manganese oxide, iron phosphate, or zeolite. To evaluate the effectiveness of these sorbents to large-scale industrial Li
2
CO
3
(or LiOH) production, we highlight their potential advantages and disadvantages in the application under geothermal operating conditions.