Characterization and Quantification of Surficial Sediment Microplastics and Its Correlation with Heavy Metals, Soil Texture, and Flow Velocity

• Published in: Analytical letters Vol. 57; no. 7; pp. 1092 - 1105
• Main Authors: Casila, J.C., Dimapilis, D.A., Limbago, J.S., Delos Reyes, A.A., Casila, E.B., Haddout, S.
• Format: Journal Article
• Language: English
• Published: Abingdon Taylor & Francis 02-05-2024; Taylor & Francis Ltd
• Subjects: Color; Correlation; Flow velocity; Heavy metals; microplastics; Pasig River; Plastic pollution; polymer; Polymers; Polyvinyl alcohol; Residential areas; sediment; Sediments; Soil properties; Soils; Texture
• ISSN: 0003-2719; 1532-236X
• DOI: 10.1080/00032719.2023.2241090

Investigating the presence of microplastics in the Pasig River, the highest plastic-emitting river in the Philippines and one of the ocean's leading contributors of these materials, is highly relevant. In this study, surficial sediments in eight stations along the main channel of the Pasig River were analyzed for microplastic content, heavy metals, and soil texture. The microplastics were categorized according to shape, color, and size. The polymer type was determined using infrared spectroscopy. The number of microplastics was correlated with heavy metals, soil texture, and flow velocity. The results show that the dominant shape, color, size, and polymer type were fragment, color white, size range from 0 to 500 μm, and polyvinyl alcohol, respectively. Downstream stations 5 and 8 had the highest microplastic concentration. The number of microplastics showed a positive moderate correlation with percent sand (r = 0.40) and clay (r = 0.42), and a negative high correlation with percent silt (r=-0.80). For microplastics and heavy metals, a positive moderate correlation was observed for iron (r = 0.52) and zinc (r = 0.58), while a negative weak correlation was present for lead (r=-0.06). Microplastics and flow velocity showed weak correlations demonstrating that the accumulation in the bottom river sediment may be based on the proximity of the plastic source rather than on the flowing water with plastic sources. Results reflect the diverse influences on the Pasig River which is surrounded by informal settlements, manufacturing industries, urban offices, and residential areas. More plastic management initiatives and better implementation of existing laws should be done by the government.