The effect of cation distribution and heat treatment temperature on the structural, surface, morphological and magnetic properties of MnxCo1−xFe2O4@SiO2 nanocomposites

• Published in: Journal of alloys and compounds Vol. 895; p. 162715
• Main Authors: Dippong, Thomas, Lazar, Mihaela Diana, Deac, Iosif Grigore, Palade, Petru, Petean, Ioan, Borodi, Gheorghe, Cadar, Oana
• Format: Journal Article
• Language: English
• Published: Lausanne Elsevier B.V 25-02-2022; Elsevier BV
• Subjects: Anisotropy; Aqueous environments; Atomic force microscopy; Cobalt ferrites; Coercivity; Fourier transforms; Heat treatment; Infrared spectroscopy; Iron; Magnetic behavior; Magnetic properties; Manganese ions; Manganese-cobalt ferrite; Morphology; Mossbauer spectroscopy; Nanocomposite; Nanocomposites; Nanoparticles; Particle size; Silicon dioxide; Spectrum analysis; Spinel; Substitutes; Nanocomposite; Spinel; Magnetic behavior; Manganese-cobalt ferrite
• ISSN: 0925-8388; 1873-4669
• DOI: 10.1016/j.jallcom.2021.162715

This paper presents the effect of Mn2+ substitution for Co2+, in CoFe2O4 embedded in SiO2 matrix, on the structural, surface, morphological and magnetic properties. X-ray diffraction (XRD) and Mössbauer spectroscopy indicate the presence of a nanocrystalline mixed cubic spinel. In all cases, for the nanocomposites (NCs) heat-treated at 200 °C, a single, low crystalline ferrite phase was remarked, while for the other heat-treatment temperatures up to 1200 °C and with increasing Mn content, the secondary phase of α-Fe2O3 appears, accompanied also by the secondary phase of SiO2 at 1200 °C. The Fourier transform infrared (FT-IR) spectroscopy confirms the consumption of starting metallic nitrates, the formation of Co-O, Mn-O, Fe-O bonds in ferrites@SiO2 matrix. The Mössbauer spectra show the characteristic magnetic patterns of Co and Mn spinels. According to the atomic force microscopy (AFM) analysis, the particle size increases from 15 to 80 nm with the increase of Mn content. The specific surface area varies in the range 150–450 m2/g due to the substitution of Co2+ ion with Mn2+ ion and decreases with increasing heat treatment temperature, reaching values below 1 m2/g at 1200 °C. All NCs have pores within the mesoporous range, with high dispersion of pores’ sizes. Furthermore, the release of fine nanoparticles in aqueous environment is facilitated by the powders’ mesoporous structure preserved at 200, 500 and 800 °C heat treatment temperatures. The porous network collapse after heat treatment at 1200 °C leads to releasing of bigger nanoparticles, in good agreement with AFM observation. Magnetization, coercivity and anisotropy evolve proportionally with the particle size for the NCs heat-treated at 800 °C (MS = 18.9–36.3 emu/g; MR = 3.05–14.1 emu/g, HC = 31.83–53.2 kA/m, K = 0.378·10−3-1.21·10−3 erg/cm−1) and inverse proportionally for those heat-treated at 1200 °C (MS = 30.7–19.4 emu/g; MR = 11.60–7.20 emu/g, Hc = 127.3–15.9 kA/m, K = 2.45·10−3-0.19·10−3 erg/cm−1). The NCs with high Mn content heat-treated at 1200 °C show superparamagnetic behavior, while those with low Mn content display ferrimagnetic behavior.
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•The crystallite size increases with increasing Mn content from 3.0 to 8.1 nm (200 °C) to 21.9–44.0 nm (1200 °C).•The surface area of NCs decreases from 335 to 460 m2/g (200 °C) to< 1 m2/g (1200 °C).•NCs treated at 1200 °C show the sextets characteristic to octahedral and tetrahedral sites of CoFe2O4 and MnFe2O4.•The magnetic properties improve with decreasing at 1200 °C particle size.•NCs at 1200 °C exhibit superparamagnetic (high Mn content) or ferromagnetic-type (low Mn content) behaviors.