A multidisciplinary approach to study precipitation kinetics and hardening in an Al-4Cu (wt. %) alloy

• Published in: Journal of alloys and compounds Vol. 757; pp. 504 - 519
• Main Authors: Rodríguez-Veiga, A., Bellón, B., Papadimitriou, I., Esteban-Manzanares, G., Sabirov, I., LLorca, J.
• Format: Journal Article
• Language: English
• Published: Lausanne Elsevier B.V 15-08-2018; Elsevier BV
• Subjects: ab initio calculations; Aging (metallurgy); Al alloy; Aluminum alloys; Aluminum base alloys; Chemical precipitation; Coherence; Copper; Dilatometry; High resolution; High resolution transmission electron microscopy; Precipitates; Precipitation hardening; Precipitation kinetics; Precipitation strengthening; Solid solutions; Thermal analysis; Transmission electron microscopy; Precipitation kinetics; ab initio calculations; High resolution transmission electron microscopy; Thermal analysis; Precipitation strengthening; Al alloy
• ISSN: 0925-8388; 1873-4669
• DOI: 10.1016/j.jallcom.2018.04.284

A multidisciplinary approach is presented to analyse the precipitation process in a model Al-Cu alloy. Although this topic has been extensively studied in the past, most of the investigations are focussed either on transmission electron microscopy or on thermal analysis of the processes. The information obtained from these techniques cannot, however, provide a coherent picture of all the complex transformations that take place during decomposition of supersaturated solid solution. Thermal analysis, high resolution dilatometry, (high resolution) transmission electron microscopy and density functional calculations are combined to study precipitation kinetics, interfacial energies, and the effect of second phase precipitates on the mechanical strength of the alloy. Data on both the coherent and semi-coherent orientations of the θ''/Al interface are reported for the first time. The combination of the different characterization and modelling techniques provides a detailed picture of the precipitation phenomena that take place during aging and of the different contributions to the strength of the alloy. This strategy can be used to analyse and design more complex alloys.
•Precipitation kinetics and hardening in Al-4%Cu is studied through a multidisciplinary approach.•Experiments and ab initio simulations are combined to give a coherent picture of the precipitation.•Interface energies and elastic constants are calculated by density functional theory.