On the mechanism of the detonation of organic high explosives

On the mechanism of the detonation of organic high explosives

This article presents a further analysis of isotopic labeling data on the mechanism of the detonation of TNT-, RDX-, and HMX-containing mixtures and on the release of free carbon from these mixtures. The distribution of carbon isotopes among the condensed explosion products and, for the first time,...

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Bibliographic Details
Published in:Russian journal of physical chemistry. B Vol. 10; no. 3; pp. 451 - 455
Main Author: Anisichkin, V. F.
Format: Journal Article
Language:English
Published: Moscow Pleiades Publishing 01-05-2016
Subjects:
Chemistry
Chemistry and Materials Science
Combustion
Explosion
Physical Chemistry
Shock Waves
detonation nanodiamond
labeled-atoms method
detonation mechanism
high explosives
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Summary:This article presents a further analysis of isotopic labeling data on the mechanism of the detonation of TNT-, RDX-, and HMX-containing mixtures and on the release of free carbon from these mixtures. The distribution of carbon isotopes among the condensed explosion products and, for the first time, among the gaseous ones is considered in relation to the particle size of the mixed explosives. A sequence of main chemical reactions in the detonation wave is suggested to account for the experimental data discussed.
ISSN:1990-7931
1990-7923
DOI:10.1134/S1990793116030155