Synthesis of an Alkylidene 2-Oxazolidinone via Gold-Catalyzed Cyclization of a N-Boc-Allenylaniline

N-Boc-allenylaniline undergoes cyclization in the presence of a catalytic amount of a cationic gold complex to exclusively form 2-oxazolidinones, whereas the N-Moc-allenylaniline affords dihydroquinolines. Supplemental materials are available for this article. Go to the publisher's online editi...

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Bibliographic Details
Published in:	Synthetic communications Vol. 43; no. 5; pp. 768 - 773
Main Authors:	De Sousa Fonseca, Flavia C., Araujo, Flavia M., Nagem, Tanus J., de Oliveira, Tânia T., Roque D. Correia, Carlos, Taylor, Jason G.
Format:	Journal Article
Language:	English
Published:	Philadelphia Taylor & Francis Group 01-01-2013 Taylor & Francis Ltd
Subjects:	2-oxazolidinones Allenes catalyst dihydroquinolines gold hydroarylation
Online Access:	Get full text
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Summary:	N-Boc-allenylaniline undergoes cyclization in the presence of a catalytic amount of a cationic gold complex to exclusively form 2-oxazolidinones, whereas the N-Moc-allenylaniline affords dihydroquinolines. Supplemental materials are available for this article. Go to the publisher's online edition of Synthetic Communications® to view the free supplemental file.
ISSN:	0039-7911 1532-2432
DOI:	10.1080/00397911.2011.623260