Application of 1-(α-Aminobenzyl)-2-naphthols as Air-Stable Ligands for Pd-Catalyzed Mizoroki-Heck Coupling Reaction

Air-stable, easily accessible Mannich bases, 1-( α -aminobenzyl)-2-naphthols, are used as ligands in palladium-catalyzed Mizoroki-Heck reaction on a variety of substrates. High turnover numbers are observed for both the reactions with aryl bromides and iodides, while aryl chlorides are inert.

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Bibliographic Details
Published in:	Synthetic communications Vol. 42; no. 12; pp. 1778 - 1785
Main Authors:	Chaudhary, Anju R., Bedekar, Ashutosh V.
Format:	Journal Article
Language:	English
Published:	Philadelphia Taylor & Francis Group 15-06-2012 Taylor & Francis Ltd
Subjects:	Aminobenzyl)-2-naphthols Chemical industry Ligands Mizoroki-Heck phosphine-free ligands
Online Access:	Get full text
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Description
Summary:	Air-stable, easily accessible Mannich bases, 1-( α -aminobenzyl)-2-naphthols, are used as ligands in palladium-catalyzed Mizoroki-Heck reaction on a variety of substrates. High turnover numbers are observed for both the reactions with aryl bromides and iodides, while aryl chlorides are inert.
ISSN:	0039-7911 1532-2432
DOI:	10.1080/00397911.2010.544439