High-precision Ramsey-comb spectroscopy on molecular deuterium for tests of molecular quantum theory

• Published in: Molecular physics Vol. 121; no. 17-18
• Main Authors: Roth, Charlaine, de Velasco, Andrés Martínez, Gründeman, Elmer L., Collombon, Mathieu, Beyer, Maximilian, Barbé, Vincent, Eikema, Kjeld S. E.
• Format: Journal Article
• Language: English
• Published: Abingdon Taylor & Francis 17-09-2023; Taylor & Francis Ltd
• Subjects: Deuterium; dissociation energy; Energy of dissociation; Free energy; Heat of formation; High-precision spectroscopy; Interrogation; ionisation energy; Ionization; Molecular beams; Quantum theory; Ramsey-comb spectroscopy; Spectroscopy; Spectrum analysis
• ISSN: 0026-8976; 1362-3028
• DOI: 10.1080/00268976.2023.2211405

Precision spectroscopy of simple, calculable molecules has become an important tool to compare experiments with theory in an effort to test our understanding of the fundamental laws of physics. For this purpose, we have measured the
  transition frequency of molecular deuterium (
) with unprecedented accuracy. We use Ramsey-Comb spectroscopy at deep-ultraviolet wavelengths (201 nm) with a two-photon, Doppler-free interrogation scheme. The resulting transition frequency is
 kHz. The 1-σ uncertainty of 19 kHz represents an improvement of more than two orders of magnitude compared to the best previous measurement. In this paper, we give an extensive description of our methods and the experimental apparatus that we employed. Particular attention is given to aspects that we recently improved, such as the frequency comb laser system, the method of signal recording, and the cryogenic
molecular beam apparatus. In combination with future measurements of the ionisation energy of the EF state, our measurement paves the way for an improved determination of the ground state ionisation and dissociation energy of molecular deuterium.