Development of LaxCa1-xMnO3 materials for Bezaktiv Blue removal in aqueous media

• Published in: Water science and technology Vol. 83; no. 11; pp. 2793 - 2808
• Main Authors: Nascimento, É. V., Garrido Pedrosa, A. M., Souza, M. J. B.
• Format: Journal Article
• Language: English
• Published: London IWA Publishing 01-06-2021
• Subjects: Adsorbents; Adsorption; Analytical methods; Aqueous solutions; bezaktiv blue; Collagen; Dyes; Electron microscopy; Electrostatic properties; Experiments; Fourier transforms; Infrared spectroscopy; Isotherms; Lanthanum compounds; Mixed oxides; modified proteic method; Nanomaterials; Nitrates; Oxides; perovskite oxide; Perovskites; Photodegradation; regeneration; reuse; Scanning electron microscopy; X-ray diffraction
• ISSN: 0273-1223; 1996-9732
• DOI: 10.2166/wst.2021.174

In this work, mixed oxides of LaxCa1-xMnO3 perovskite type (x = 0, 0.5 and 1.0) were synthesized through modified proteic method using collagen and calcination process at 700 °C/2 h in order to remove the commercial textile dye Bezaktiv Blue S-MAX from water. Oxides were characterized using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), N2 physisorption, scanning electron microscopy (SEM) and point of zero charge (PZC) techniques while the dye only by the first two techniques. The XRD showed that perovskite monophase was obtained for x = 0.5 and 1.0. However, for x = 0, the low crystalline perovskite phase was obtained in the midst of precursor oxides. FTIR showed the adsorption process did not damage the adsorbents structure. The successful obtained materials have meso and macroporous with slit or cavity shape, rough surface and particles with varying sizes. The pseudo-second-order model was the one that best fit the kinetic data. The process must occur through electrostatic surface interactions between the adsorbent surface and the dye molecule. For the equilibrium study, Langmuir isotherm is the most suitable when using LaMnO3 adsorbent, while Freundlich isotherm was better suited when used the other two materials. The adsorbents were termally regenerated and reused five times. The best performance was exhibited by LaMnO3.