Fouling tendency of bitumen visbreaking products

• Published in: Fuel (Guildford) Vol. 289; p. 119735
• Main Authors: Xing, Tingyong, Ali, Mohamed, Alem, Teclemariam, Gieleciak, Rafal, Chen, Jinwen
• Format: Journal Article
• Language: English
• Published: Kidlington Elsevier Ltd 01-04-2021; Elsevier BV
• Subjects: Alkenes; Asphaltenes; Bitumen; Bitumens; Blending; Fouling; Fouling tendency; Oil sands; Olefins; Visbreaking; Asphaltenes; Fouling tendency; Olefins; Visbreaking; Bitumen
• ISSN: 0016-2361; 1873-7153
• DOI: 10.1016/j.fuel.2020.119735

•Fouling tendency of bitumen visbreaking products was investigated.•The contributions of olefin and asphaltene to fouling tendency were presented.•Fouling tendency changed with pitch conversion linearly.•Deasphalting significantly reduced the fouling tendency of the visbreaking product.•The effect of olefin on fouling tendency was limited at reduced asphaltene content.
In this work, the fouling behaviour of thermally processed bitumen products obtained by visbreaking was studied. The feedstock was prepared by blending raw oil sands bitumen with 15 vol% hydrotreated light oil (HLO). The visbreaking products obtained at different pitch (525 °C + fraction) conversions were characterized and tested for fouling tendency. Test results showed that the fouling tendency linearly increased with total olefin content in visbreaking products. To further investigate the separate contributions of olefins and asphaltenes to fouling tendency, a selected visbreaking product was distilled into an olefin-rich 280 °C − fraction and a “heavy” 280 °C + fraction to avoid the loss of lighter fractions during the deasphalting process. To minimize the effect of interactions between olefins and asphaltenes on the fouling tendency, the 280 °C − fraction was hydrotreated and the 280 °C + fraction deasphalted. The deasphalted samples with different olefin contents and the hydrotreated samples with different asphaltene contents were obtained by blending the processed 280 °C − and 280 °C + fractions. Test results showed that deasphalting significantly reduced the fouling tendency of the visbreaking product. In the presence of olefins, asphaltenes have a significant effect on the fouling tendency of thermally processed products, whereas in the absence of olefins, the impact of asphaltenes on fouling tendency was limited. Similarly, olefins have a limited effect on the fouling tendency of visbreaking product in the absence of asphaltenes.