Screening cost effectiveness and salinity build up control in osmotic membrane bioreactors for refinery wastewater treatment: A draw solute with lower diffusivity and ultrafiltration implementation

• Published in: Process safety and environmental protection Vol. 151; pp. 195 - 207
• Main Authors: Lebron, Yuri Abner Rocha, Moreira, Victor Rezende, Moser, Priscila Barbosa, de Souza Santos, Lucilaine Valéria, Amaral, Miriam Cristina Santos
• Format: Journal Article
• Language: English
• Published: Rugby Elsevier B.V 01-07-2021; Elsevier Science Ltd
• Subjects: Accumulation; Bioreactors; Cost effectiveness; Diffusivity; Dissolved organic carbon; Draw solution; Fluctuations; Flux; Hybrid UF-OMBR; Magnesium chloride; Membranes; OMBR; Operating costs; Osmosis; Recalcitrant compounds; Refineries; Refinery wastes; Salinity; Salinity build up; Salinity effects; Sodium chloride; Ultrafiltration; Wastewater treatment; Salinity build up; Draw solution; Hybrid UF-OMBR; OMBR; Wastewater treatment; Recalcitrant compounds
• ISSN: 0957-5820; 1744-3598
• DOI: 10.1016/j.psep.2021.05.018

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Two strategies were investigated for salinity build up prevention in osmotic membrane bioreactors (OMBR) treating a real refinery wastewater. Firstly, a solute with lower diffusivity (MgCl2, for 102 days) was used. The impact on the microbiological activity was lower, which favored the recalcitrant compounds degradation. However, without salinity relief, the mixed liquor (ML) salinity increased, impacting the forward osmosis (FO) flux (0.18 L/m2h). Secondly, an ultrafiltration (UF) membrane was submerged within the ML and the draw solution (DS) replaced to NaCl. The ML conductivity was stable along 330 days without a severe flux decay (1.07 L/m2h). Nonetheless, the reverse NaCl flux had a higher impact on the microbiological activity and the concentration of dissolved organic carbon and ammoniacal nitrogen started to increase in the UF permeate. Due to the lower permeate flux, the OMBR had a higher membrane area requirement which represented the main contributor for the total operating costs.