High‐Throughput Study of Amorphous Stability and Optical Properties of Superlattice‐Like Ge–Sb–Te Thin Films

• Published in: Small (Weinheim an der Bergstrasse, Germany) Vol. 20; no. 16; pp. e2307792 - n/a
• Main Authors: Hui, Jian, Hu, Qingyun, Yuan, Hongjian, Shi, Ruiqian, Huang, Xiang, Wu, Yuanyuan, Ren, Yang, Zhang, Zhan, Wang, Hong
• Format: Journal Article
• Language: English
• Published: Germany Wiley Subscription Services, Inc 01-04-2024
• Subjects: Amorphous materials; amorphous stability; Annealing; Antimony; Chemical composition; Combinatorial analysis; Ge–Sb–Te; high‐throughput; Ion beam sputtering; Metastable phases; Modulation; Optical properties; Phase diagrams; Stability; Superlattices; super‐lattice like; Tellurium; Thin films; super‐lattice like; optical properties; high‐throughput; amorphous stability; Ge–Sb–Te
• ISSN: 1613-6810; 1613-6829
• DOI: 10.1002/smll.202307792

A high‐throughput ion beam sputtering system is used to synthesize compositional gradient superlattice‐like (SLL) thin film libraries of Ge–Sb–Te alloys over the entire phase diagram. The optical properties and structural evolution of the Ge–Sb–Te combinatorial SLL thin film are investigated. A systematic screening over the annealing temperature, annealing time, and modulation period has elucidated the critical factors that affect the stability of the metastable phase and optical properties. It is found that amorphous stability and optical constant are highly dependent on the modulation period and chemical composition of the thin film. This data‐driven approach offers new perspectives for accelerating the development of new materials with excellent optical and amorphous stability and for exploring their mechanisms, by greatly expanding the dataset of Ge–Sb–Te alloys with SLL structures through high‐throughput experiments.
A batch experimental data‐driven approach integrating combinatorial Ge–Sb–Te superlattice‐like (SLL) thin film preparation, high‐throughput characterization, and data analysis for rapid screening of amorphous stable and optically superior optical phase change material thin films with SLL structures.