A one-pot, two-step reaction for the synthesis of VLC acidic polymers for resin modified glass-ionomers

Methacrylate‐functionalized aromatic oxazolines are evaluated for attaching pendant methacrylate groups to acid containing polymers. Typically, these reactions use the toxic liquid 2‐isocyanatoethyl methacrylate (IEM) to functionalized the acid containing polymer. Methacrylate‐functionalized oxazoli...

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Bibliographic Details
Published in:	Polymers for advanced technologies Vol. 12; no. 6; pp. 387 - 390
Main Authors:	Schricker, S. R., Dotrong, M. H., Huang, Y., Culbertson, B. M.
Format:	Journal Article
Language:	English
Published:	Chichester, UK John Wiley & Sons, Ltd 01-06-2001
Subjects:	oxazolines physical testing poly(acrylic acid) resin modified glass-ionomers
Online Access:	Get full text
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Summary:	Methacrylate‐functionalized aromatic oxazolines are evaluated for attaching pendant methacrylate groups to acid containing polymers. Typically, these reactions use the toxic liquid 2‐isocyanatoethyl methacrylate (IEM) to functionalized the acid containing polymer. Methacrylate‐functionalized oxazolines will add to acid containing polymer in aqueous solvent. Thus, in a one‐pot, two‐step reaction the acid containing polymer can be synthesized and then reacted with the methacrylate‐functionalized oxazoline. The visible light‐curable (VLC) polymer can then be formulated in resin modified glass‐ionomers. The resulting glass‐ionomers have properties that are comparable to commercial materials. Copyright © 2001 John Wiley & Sons, Ltd.
Bibliography:	istex:BC38B402CC6E0F4C1B743FA2E7A4A252EBF53443 ArticleID:PAT121 ark:/67375/WNG-VH6CNFT9-Z ObjectType-Article-2 SourceType-Scholarly Journals-1 ObjectType-Feature-1 content type line 23
ISSN:	1042-7147 1099-1581
DOI:	10.1002/pat.121