Remote Participation-Assisted Synthesis of β-Mannosides

Remote Participation-Assisted Synthesis of β-Mannosides

The stereoselectivity of β‐mannosylation can be improved with the use of a participating moiety at C‐4 (O‐anisoyl, O‐thiocarbamoyl). This improvement was achieved in glycosidations of S‐ethyl and, especially, S‐benzoxazolyl (SBox) mannosides. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim,...

Full description

Saved in:
Bibliographic Details
Published in:European Journal of Organic Chemistry Vol. 2005; no. 4; pp. 706 - 711
Main Authors: De Meo, Cristina, Kamat, Medha N., Demchenko, Alexei V.
Format: Book Review Journal Article
Language:English
Published: Weinheim WILEY-VCH Verlag 01-02-2005
WILEY‐VCH Verlag
Subjects:
Carbohydrates
Glycosylation
Remote participation
Stereoselective synthesis
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The stereoselectivity of β‐mannosylation can be improved with the use of a participating moiety at C‐4 (O‐anisoyl, O‐thiocarbamoyl). This improvement was achieved in glycosidations of S‐ethyl and, especially, S‐benzoxazolyl (SBox) mannosides. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)
Bibliography:ArticleID:EJOC200400616
istex:75593D229CAC70AA61731CCD7264479044EBA37B
ark:/67375/WNG-1V0KC4M6-M
ISSN:1434-193X
1099-0690
DOI:10.1002/ejoc.200400616