Carbon dots prepared by solid state method via citric acid and 1,10-phenanthroline for selective and sensing detection of Fe2+ and Fe3

• Published in: Sensors and actuators. B, Chemical Vol. 237; pp. 408 - 415
• Main Authors: Iqbal, Anam, Tian, Yuejun, Wang, Xudong, Gong, Deyan, Guo, Yali, Iqbal, Kanwal, Wang, Zhiping, Liu, Weisheng, Qin, Wenwu
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01-12-2016
• Subjects: Actuators; Carbon; Carbon dots; Cell imaging; Citric acid; Fe2; Fe3; Fluorescence; Fluorescent detection; Nanoparticles; Selectivity; Sensors; Solid state; Solid state method; Fluorescent detection; Fe2; Solid state method; Carbon dots; Cell imaging; Fe3
• ISSN: 0925-4005; 1873-3077
• DOI: 10.1016/j.snb.2016.06.126

The CDs (CA+Phen) could be potentially utilized as an excellent optical sensor for the quantitative analysis of Fe2+ or Fe3+ in living cells.
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•CDs (CA+Phen) was successfully prepared by the one step solid state method.•Fe2+ and Fe3+ can effectively quench the fluorescence of CDs (CA+Phen).•CDs (CA+Phen) shows remarkable properties including very fast and simple, one step, cost-effective as well as environmental-friendly.•CDs (CA+Phen) can be use for detecting Fe in cell and milk.
A new kind of convenient, low-cost, environmentally friendly, and simple one step synthetic route for the preparation of C-dots-based CDs (CA+Phen) fluorescent turn-off probe for Fe2+ and Fe3+ from 1,10-phenanthroline (Phen) using anhydrous citric acid (CA) as the sole precursor without any solvents by solid state method. Only the Fe2+ and Fe3+ can readily quench the fluorescence of the CDs (CA+Phen), indicating a remarkably high selectivity towards Fe2+ and Fe3+ over other metals with a detection limit as low as 20nM and 35nM. The CDs (CA+Phen) exhibited a low cytotoxicity and could label the HK-2 cells. Additionally, this CDs (CA+Phen) has been successfully applied for the determination of Fe in real sample of milk. Endowed with relatively high sensitivity and selectivity, the present sensor holds the potential to be applied for the detection of Fe2+ and Fe3+ in aqueous media.