A Cerium Hexacyanoferrate (III) Nanoparticle‐modified Carbon Paste Electrode: Voltammetric Characterization and Behavior in the Presence of Dopamine

• Published in: Electroanalysis (New York, N.Y.) Vol. 32; no. 7; pp. 1524 - 1532
• Main Authors: Oliveira, Denys Ribeiro, Fernandes, Daniela Silvestrini, Carmo, Devaney Ribeiro
• Format: Journal Article
• Language: English
• Published: 01-07-2020
• Subjects: Cerium hexacyanoferrate (II) nanoparticles; Differential pulse voltammetry; Dopamine; Electrochemical Sensor
• ISSN: 1040-0397; 1521-4109
• DOI: 10.1002/elan.201900441

This study describes a fast and simple methodology for the preparation of Cerium (III) Hexacyanoferrate (II) (CeHCF) nanoparticles (NPs). The NPs were characterized by fourier transform infrared (FTIR), x‐ray diffraction (XRD), scanning electron microscopy (SEM) and cyclic voltammetry (CV). The CeHCF cyclic voltammogram indicate a well‐defined redox pair assigned as Fe2+/Fe3+ in the presence of cerium (III), with a formal potential of Eθ′=0.29 V (v=100 mV s−1, KNO3; 1.0 mol/L, pH 7.0). The carbon paste electrode modified with CeHCF (CeHCF‐CPE) was applied to the catalytic electrooxidation of dopamine applying Differential Pulse Voltammetry (DPV). DPV showed linear response at two concentration ranges, from 9.0×10−7 to 8.0×10−6 and 9.0×10−6 to 1.0×10−4 mol/L, with an LOD of 1.9×10−7 and 1.0×10−5 mol/L, respectively. The CeHCF‐CPE exhibited selectivity against substances commonly found in biological samples, with redox potentials close to that of dopamine, such as urea and ascorbic acid (AA). Subsequently the CeHCF‐CPE was successfully applied to the detection of dopamine in simulated urine samples, with recovery percentages ranging between 99 and 103%.