Model of Reactant Adsorption in dc Polarography

An expanding plane model of polarogram influenced by the reactant adsorption is developed and applied to the Frumkin isotherm. It is shown that the polarogram may consist of the main wave and post-wave that are separated by the maximum and minimum. The origin of these extremes are investigated by th...

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Bibliographic Details
Published in:	Croatica Chemica Acta Vol. 93; no. 3; pp. 1 - 7
Main Author:	Lovric, Milivoj
Format:	Journal Article Paper
Language:	English
Published:	Zagreb Croatica Chemica Acta 01-12-2021 Croatica Chemica Acta, Croatian Chemical Society Hrvatsko kemijsko društvo
Subjects:	Adsorption adsorption of reactant dc polarography Electrodes expanding plane model Mercury Polarography
Online Access:	Get full text
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Summary:	An expanding plane model of polarogram influenced by the reactant adsorption is developed and applied to the Frumkin isotherm. It is shown that the polarogram may consist of the main wave and post-wave that are separated by the maximum and minimum. The origin of these extremes are investigated by the calculation of currents that flow during a single mercury drop. Keywords: adsorption of reactant, dc polarography, expanding plane model.
Bibliography:	255661
ISSN:	0011-1643 1334-417X
DOI:	10.5562/cca3736