Three Mechanisms in One Material: Uranium Capture by a Polyoxometalate–Organic Framework through Combined Complexation, Chemical Reduction, and Photocatalytic Reduction

• Published in: Angewandte Chemie International Edition Vol. 58; no. 45; pp. 16110 - 16114
• Main Authors: Zhang, Hailong, Liu, Wei, Li, Ao, Zhang, Duo, Li, Xiaoyan, Zhai, Fuwan, Chen, Lanhua, Chen, Long, Wang, Yanlong, Wang, Shuao
• Format: Journal Article
• Language: English
• Published: Germany Wiley Subscription Services, Inc 04-11-2019
• Edition: International ed. in English
• Subjects: Chemical reduction; Complexation; Irradiation; Light irradiation; metal–organic frameworks; Organic chemistry; Photocatalysis; Photoelectron spectroscopy; Photoelectrons; polyoxometalates; Polyoxometallates; Radiation; Radiation tolerance; reduction; Selectivity; Sorbents; Sorption; Uranium; uranium; photocatalysis; reduction; polyoxometalates; metal-organic frameworks
• ISSN: 1433-7851; 1521-3773
• DOI: 10.1002/anie.201909718

The design and synthesis of uranium sorbent materials with high uptake efficiency, capacity and selectivity, as well as excellent hydrolytic stability and radiation resistance remains a challenge. Herein, a polyoxometalate (POM)–organic framework material (SCU‐19) with a rare inclined polycatenation structure was designed, synthesized through a solvothermal method, and tested for uranium separation. Under dark conditions, SCU‐19 can efficiently capture uranium through ligand complexation using its exposed oxo atoms and partial chemical reduction from UVI to UIV by the low‐valent Mo atoms in the POM. An additional UVI photocatalytic reduction mechanism can occur under visible light irradiation, leading to a higher uranium removal without saturation and faster sorption kinetics. SCU‐19 is the only uranium sorbent material with three distinct sorption mechanisms, as further demonstrated by X‐ray photoelectron spectroscopy (XPS) and X‐ray absorption near edge structure (XANES) analysis.
Stuck on U: Uranium capture by a polyoxometalate–organic framework is possible through three different mechanisms, these are complexation, chemical reduction, and photocatalytic reduction. The material features a unique 2D+2D→3D polycatenation structure, resulting in excellent stability toward hydrolysis and ionization irradiation.