Chemical fingerprinting and characterization of spilled oils and burnt soot particles – A case study on the Sanchi oil tanker collision in the East China Sea

• Published in: The Science of the total environment Vol. 824; p. 153896
• Main Authors: Yin, Fang, Song, Zhibo, He, Zhiwei, Qin, Boyu, John, Gerald F., Zhang, Li, Su, Penghao, Zhang, Wenshu, Yang, Tao
• Format: Journal Article
• Language: English
• Published: Netherlands Elsevier B.V 10-06-2022
• Subjects: China; Combustion; Diagnostic ratio; Fingerprint; Oil spill; Oils; Pentacyclic Triterpenes; Petroleum - analysis; Petroleum Pollution - analysis; Polycyclic Aromatic Hydrocarbons - analysis; Sanchi; Soot; Water Pollutants, Chemical - analysis; China; Oil spill; Sanchi; Fingerprint; Diagnostic ratio; Combustion; Soot
• ISSN: 0048-9697; 1879-1026
• DOI: 10.1016/j.scitotenv.2022.153896

The condensate spill accident from the Sanchi oil tanker collision in the East China Sea is unique in world history. To date, the spilled and burnt amounts of condensate remain unknown. The present study demonstrates the chemical fingerprints of a surrogate condensate (SC) from the same source, and of the carried heavy fuel oil (HFO) of the Sanchi accident. The evaporative features of the condensate are demonstrated by allowing the SC to naturally volatilize in a dark fume hood. In addition, the combustion emission of the SC is characterized by conducting a laboratory-scale combustion experiment. The evaporation experiment suggests that the volatilization process plays a significant role in the weathering of the condensate. The results show that the SC and HFO can be clearly distinguished based on their chemical fingerprints of C27–C35 hopanes and C9–C36 n-alkanes, along with priority polycyclic aromatic hydrocarbons (PAHs) and their alkylated derivatives. The compositional data reveal that the lighter component is predominant in the SC, thereby supporting its high volatility and flammability. The greater amounts of heavier components in the HFO indicate its long-term degradation and potential ecological risks to the environment. Further, the trisnorhopane thermal indicator (Ts/Tm) and C29/C30 ratio of hopanes are validated for identification of the SC and the HFO. More importantly, the changes in the hopane ratios of the soot particles are analyzed for the first time in this study, and the results demonstrate the validity of using hopane ratios to fingerprint the condensate soot particles. The diagnostic ratios of 2-MP/1-MP, 9/4-MP/1-MP, and InP/(InP+BghiP) also show decent performance on source identification after the condensate evaporation and combustion processes.
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•Chemical fingerprints of hopanes, n-alkanes, parent and alkylated PAHs in the Sanchi spilled oils are presented•Evaporation must be significant for condensate weathering on the sea surface•Stable diagnostic ratios of the hopanes are found in the soot from the burnt condensate•The stability of the source-specific ratios of PAHs are studied in the evaporated condensate and burnt soot