Preparation, thermo-optic property and simulation of optical switch based on azo benzothiazole polymer

• Published in: Applied physics. B, Lasers and optics Vol. 111; no. 1; pp. 93 - 102
• Main Authors: Cao, Zhijuan, Qiu, Fengxian, Wang, Qing, Cao, Guorong, Guan, Yijun, Zhuang, Lin, Xu, Xiaolong, Wang, Jie, Chen, Qian, Yang, Dongya
• Format: Journal Article
• Language: English
• Published: Berlin/Heidelberg Springer-Verlag 01-04-2013
• Subjects: Azo; Charge coupled devices; Chromophores; Engineering; Interferometers; Lasers; Mathematical analysis; Optical Devices; Optics; Photonics; Physical Chemistry; Physics; Physics and Astronomy; Polymerization; Quantum Optics; Simulation; Switches; Isophorone Diisocyanate; Diazenyl; Attenuate Total Reflection Spectrum; Transmission Loss; Benzothiazole
• ISSN: 0946-2171; 1432-0649
• DOI: 10.1007/s00340-012-5311-3

An azo chromophore molecule 4-[(benzothiazole-2-yl)diazenyl]phenyl-1,3-diamine (BTPD) was prepared with 2-amino benzothiazole and
m
-phenylenediamine by diazo-coupling reaction. Then, the chromophore molecule BTPD was polymerized with NJ-210 and isophorone diisocyanate (IPDI) to obtain novel azo benzothiazole polymer (BTPU). The structures of BTPD and BTPU were characterized using the Fourier transform infrared, UV–visible spectroscopy, DSC and TGA. The physical properties of the obtained BTPU were investigated. The refractive index (
n
) of BTPU was demonstrated at different temperature and wavelength (532, 650 and 850 nm) using attenuated total reflection technique. The transmission loss and dispersion characteristic of BTPU film were investigated using the CCD digital imaging devices and Sellmeyer equation. A Y-branch and 2 × 2 Mach–Zehnder interferometer (MZI) polymeric thermo-optic switches based on the thermo-optic effect of prepared BTPU were proposed and the performance of switches was simulated. The results indicated that the power consumption of the Y-branch thermo-optic switch could be only 0.6 mW. The Y-branch and MZI switching rising and falling times obtained were 8.0 and 1.8 ms.