Direct synthesis of pure brannerite UTi2O6

• Published in: Journal of nuclear materials Vol. 515; pp. 401 - 406
• Main Authors: Mesbah, Adel, Szenknect, Stéphanie, Clavier, Nicolas, Lin, Hantao, Baron, Fabien, Beaufort, Daniel, Batonneau, Yann, Mercadier, Julien, Eglinger, Aurélien, Turuani, Marion, Goncalves, Philippe, Choulet, Flavien, Chapon, Virginie, Seydoux-Guillaume, Anne-Magali, Pagel, Maurice, Dacheux, Nicolas
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01-03-2019; Elsevier
• Subjects: Brannerite; Chemical Sciences; Uranium hydroxide; Uranium titanate; Brannerite; Uranium titanate; Uranium hydroxide; uranium hydroxide Corresponding author
• ISSN: 0022-3115; 1873-4820
• DOI: 10.1016/j.jnucmat.2019.01.003

A new method based on the precipitation of uranium(IV) and titanium(IV) hydroxide precursors was developed to prepare pure brannerite UTi2O6 samples. In fact, U(IV) dissolved in HCl (6 mol L−1) was mixed to Ti (IV) alkoxyde before a basification step with an excess of NH4OH to obtain a highly reactive nanometric (U,Ti)(OH)4 powder. The obtained powder was then dried under vacuum, pressed into pellets and finally fired at 1300 °C. This method led to the formation of pure brannerite in contrast to previous reported protocols, which showed the formation of impurities such us UO2 and TiO2. The refined unit cell parameters of UTi2O6 led to a = 9.8113(2) Å, b = 3.7681(1) Å, c = 6.9232(1) Å, β = 118.94(1)° and V = 223.9(1) Å3.
•Single phase brannerite UTi2O6 samples have been prepared at 1300 °C under argon atmosphere.•One-step synthesis of brannerite has been developed from uranium-titanium hydroxide precursor.•XRD and spectroscopic characterization of the samples have been performed.