Thermo-kinetic investigation of the multi-step pyrolysis of smoked cigarette butts towards its energy recovery potential

• Published in: Biomass conversion and biorefinery Vol. 12; no. 3; pp. 741 - 755
• Main Authors: Alves, José Luiz Francisco, da Silva, Jean Constantino Gomes, Mumbach, Guilherme Davi, da Silva Filho, Valdemar Francisco, Di Domenico, Michele, de Sena, Rennio Felix, Bolzan, Ariovaldo, Machado, Ricardo Antonio Francisco, Marangoni, Cintia
• Format: Journal Article
• Language: English
• Published: Berlin/Heidelberg Springer Berlin Heidelberg 01-03-2022; Springer Nature B.V
• Subjects: Biofuels; Biotechnology; Cellulose acetate; Cellulose fibers; Cigarettes; Conversion; Devolatilization; Energy; Energy recovery; Energy value; Original Article; Pyrolysis; Renewable and Green Energy; Thermogravimetry; Tobacco; Deconvolution process; Energy recovery; Smoked cigarette butts; Pyrolysis kinetics; Thermodynamics analysis
• ISSN: 2190-6815; 2190-6823
• DOI: 10.1007/s13399-020-01077-2

The present study attempts to explore the energy potential of smoked cigarette butts (SCB) through pyrolysis. For the first time, the pyrolysis characteristics, including the kinetic triplet and the thermodynamic parameters, were investigated using non-isothermal thermogravimetry. Firstly, three pseudo-components were successfully deconvoluted from the multiple-step pyrolysis of SCB using the asymmetrical Fraser-Suzuki function, which corresponds to the devolatilization reactions of retained organic volatile components (PS-1), unburned tobacco (PS-2), and cellulose acetate fibers (PS-3). Posteriorly, the isoconversional methods of Friedman, Flynn-Wall-Ozawa, Kissinger-Akahira-Sunose, and Starink were used to obtain the activation energy values, which were lower for PS-1 (from 101.87 to 108.77 kJ mol
−1
). The frequency factor values for SCB pyrolysis determined by the compensation effect method were 1.77 × 10
12
min
−1
for PS-1, 9.44 × 10
16
min
−1
for PS-2, and 9.62 × 10
20
min
−1
for PS-3. According to the master plot method, the three pseudo-components followed
n
th-order reaction models. An acceptable correspondence was observed between experimental and reconstructed pyrolysis behavior, proving the representativity and reliability of the obtained kinetic triplets. Both positive values of Δ
H
and Δ
G
suggest that the pyrolytic conversion of smoked cigarette butts into biofuels can be considered as a non-spontaneous conversion. These pyrolysis-related findings from SCB can be used to offer a good opportunity for its valorization as an energy commodity instead of a neglected solid residue.
Graphical abstract