Thermal steam methane reforming over bimetal-loaded hemp-derived activated carbon-based catalyst for hydrogen production

• Published in: Research on chemical intermediates Vol. 49; no. 7; pp. 3181 - 3203
• Main Authors: Minhas, Rashid, Khoja, Asif Hussain, Naeem, Nida, Anwar, Mustafa, Shakir, Sehar, Liaquat, Rabia, Din, Israf Ud
• Format: Journal Article
• Language: English
• Published: Dordrecht Springer Netherlands 01-07-2023; Springer Nature B.V
• Subjects: Activated carbon; Bimetals; Catalysis; Catalysts; Chemical synthesis; Chemistry; Chemistry and Materials Science; Cobalt; Conversion; Crystallites; Fixed bed reactors; Fixed beds; Hemp; Hydrogen production; Inorganic Chemistry; Methane; Physical Chemistry; Reforming; Hemp; Hydrogen; Activated carbon; Steam methane reforming
• ISSN: 0922-6168; 1568-5675
• DOI: 10.1007/s11164-022-04924-1

Ni-Co loaded hemp-derived activated carbon (AC) catalyst is synthesized by the wet impregnation method for steam methane reforming (SMR) for hydrogen production. The monometallic and bimetallic metal (Co, Ni) catalysts were synthesized over activated AC with 5 wt% by the wet impregnation method and characterized by using various techniques. XRD and SEM results suggested that the catalysts with small metal crystallites promote a better dispersion of highly porous AC.The catalytic assessment of all synthesized catalysts for SMR was carried out in a thermal fixed bed reactor at 750 °C, WHSV 2000 mL CH
4
g
−1
 h
−1
, and S/C of 2.0. The catalytic results showed that among all the investigated samples, monometallic cobalt catalyst (5% Co@AC) exhibited the best results in terms of CH
4
conversion (97.17%) and H
2
production (66.08%). While the 5% Ni@AC and 5% NiCo@AC show a CH
4
conversion of 90.28% and 92.52%, respectively, whereas the H
2
production was 61.02% and 65.89%.