Application of the dressed-bound-state molecular strong-field approximation to above-threshold ionization of heteronuclear molecules: NO vs. CO

• Published in: The Journal of chemical physics Vol. 137; no. 13; p. 134307
• Main Authors: Busuladžić, M, Hasović, E, Becker, W, Milošević, D B
• Format: Journal Article
• Language: English
• Published: United States 07-10-2012
• Subjects: Carbon Monoxide - chemistry; Nitric Oxide - chemistry; Quantum Theory
• ISSN: 1089-7690
• DOI: 10.1063/1.4757255

We theoretically investigate high-order above-threshold ionization (HATI) of heteronuclear diatomic molecules applying the molecular strong-field approximation which includes dressing of the molecular bound state. We consider HATI of nitrogen monoxide molecules, which are characterized by the π symmetry of their highest occupied molecular orbital. We show that the HATI spectra of NO exhibit characteristic interference structures. We analyze the differences and similarities of the HATI spectra of NO molecules and the spectra of CO (σ symmetry) and O(2) (π(g) symmetry) molecules. The symmetry properties of the molecular HATI spectra governed by linearly and elliptically polarized fields are considered in detail. The yields of high-energy electrons, contributing to the plateau region of the photoelectron spectra, strongly depend on the employed ellipticity.