Palladium‐Catalyzed Tandem γ‐Arylation/Aromatization of Cyclohex‐2‐En‐1‐One Derivatives: A Route to 3,4‐Dihydroanthracen‐1(2H)‐Ones

Palladium‐Catalyzed Tandem γ‐Arylation/Aromatization of Cyclohex‐2‐En‐1‐One Derivatives: A Route to 3,4‐Dihydroanthracen‐1(2H)‐Ones

An intramolecular palladium‐catalyzed tandem γ‐arylation/aromatization reaction of cyclohex‐2‐en‐1‐one derivatives was developed. This work provides a simple and efficient approach for the construction of substituted 3,4‐dihydroanthracen‐1(2H)‐ones in good yields with a broad substrate scope....

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Bibliographic Details
Published in:Advanced synthesis & catalysis Vol. 363; no. 12; pp. 3001 - 3005
Main Authors: Song, Yi‐Kang, Xu, Si‐Yu, Zhang, Shu‐Sheng, Fu, Jian‐Guo, Lin, Guo‐Qiang, Feng, Chen‐Guo
Format: Journal Article
Language:English
Published: Heidelberg Wiley Subscription Services, Inc 21-06-2021
Subjects:
cyclization
dihydroanthracen-1(2H)-ones
Palladium
Substrates
tandem reactions
γ-arylation
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Summary:An intramolecular palladium‐catalyzed tandem γ‐arylation/aromatization reaction of cyclohex‐2‐en‐1‐one derivatives was developed. This work provides a simple and efficient approach for the construction of substituted 3,4‐dihydroanthracen‐1(2H)‐ones in good yields with a broad substrate scope.
ISSN:1615-4150
1615-4169
DOI:10.1002/adsc.202001587