Triple Interface Optimization of Ru‐based Electrocatalyst with Enhanced Activity and Stability for Hydrogen Evolution Reaction

• Published in: Advanced functional materials Vol. 33; no. 13
• Main Authors: Li, Guozheng, Sun, Tong, Niu, Hua‐Jie, Yan, Yu, Liu, Tong, Jiang, Sisi, Yang, Qinglin, Zhou, Wei, Guo, Lin
• Format: Journal Article
• Language: English
• Published: Hoboken Wiley Subscription Services, Inc 01-03-2023
• Subjects: activity; Dissolution; Electrical resistivity; Electrocatalysts; Hydrogen evolution reactions; interface optimization; Interface stability; Interfaces; Materials science; Molybdenum disulfide; Optimization; Oxidation; Phase stability; stability
• ISSN: 1616-301X; 1616-3028
• DOI: 10.1002/adfm.202212514

A challenging task is to promote Ru atom economy and simultaneously alleviate Ru dissolution during the hydrogen evolution reaction (HER) process. Herein, Ru nanograins (≈1.7 nm in size) uniformly grown on 1T‐MoS2 lace‐decorated Ti3C2Tx MXene sheets (Ru@1T‐MoS2‐MXene) are successfully synthesized with three types of interfaces (Ru/MoS2, Ru/MXene, and MoS2/MXene). It gives high mass activity of 0.79 mA µgRu−1 at an overpotential of 100 mV, which is ≈36 times that of Ru NPs. It also has a much smaller Ru dissolution rate (9 ng h−1), accounting for 22% of the rate for Ru NPs. Electrochemical tests, scanning electrochemical microscopy measurements combined with DFT calculations disclose the role of triple interface optimization in improved activity and stability. First, 2D MoS2 and MXene can well disperse and stabilize Ru grains, giving larger electrochemical active area. Then, Ru/MoS2 interfaces weakening H* adsorption energy and Ru/MXene interfaces enhancing electrical conductivity, can efficiently improve the activity. Next, MoS2/MXene interfaces can protect MXene sheet edges from oxidation and keep 1T‐MoS2 phase stability during the long‐term catalytic process. Meanwhile, Ru@1T‐MoS2‐MXene also displays superior activity and stability in neutral and alkaline media. This work provides a multiple‐interface optimization route to develop high‐efficiency and durable pH‐universal Ru‐based HER electrocatalysts.
The hybrid catalyst of Ru@1T‐MoS2‐MXene with three types of interfaces (Ru/MoS2, Ru/MXene, and MoS2/MXene), gives 36 times higher mass activity and ≈5 times enhanced durability compared with Ru because of the weakened H* adsorption energy, increased conductivity, stabilized MXene, and 1T‐MoS2, and decreased Ru dissolution endowed by multi‐functional interfaces.