Synthesis of functionalized trimethylsilyl aminomethylphosphinates containing triethoxysilyl moieties

Synthesis of functionalized trimethylsilyl aminomethylphosphinates containing triethoxysilyl moieties

A convenient synthesis of functionalized trimethylsilyl aminomethylphosphinates containing triethoxysilyl moieties was developed. Radical addition of bis(trimethylsiloxy)-phosphine to triethoxy(vinyl)silane proceeds regioselectively to afford a novel synthon, (2-triethoxysilylethyl)phosphonite, subs...

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Bibliographic Details
Published in:Russian chemical bulletin Vol. 72; no. 4; pp. 1088 - 1092
Main Authors: Prishchenko, A. A., Livantsov, M. V., Novikova, O. P., Livantsova, L. I., Baranin, S. V., Bubnov, Yu. N.
Format: Journal Article
Language:English
Published: New York Springer US 01-04-2023
Springer Nature B.V
Subjects:
Brief Communications
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Inorganic Chemistry
Organic Chemistry
Phosphines
Synthesis
organophosphorus compounds
aminomethylphosphinic acids
biologically active substances
radical addition
bis(trimethylsiloxy)phosphine
aminomethylation
triethoxy(vinyl)silane
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Summary:A convenient synthesis of functionalized trimethylsilyl aminomethylphosphinates containing triethoxysilyl moieties was developed. Radical addition of bis(trimethylsiloxy)-phosphine to triethoxy(vinyl)silane proceeds regioselectively to afford a novel synthon, (2-triethoxysilylethyl)phosphonite, subsequent aminomethylation of which gives the target phosphinates.
ISSN:1066-5285
1573-9171
DOI:10.1007/s11172-023-3875-3