Measurement and Calculation the Excess Molar Properties of Binary Mixtures Containing Isobutanol, 1-Amino-2-Propanol, and 1-Propanol at Temperatures of (293.15 to 333.15) K

• Published in: Journal of solution chemistry Vol. 46; no. 2; pp. 446 - 460
• Main Authors: Kermanpour, F., Ettefagh, T. S., Iloukhani, H.
• Format: Journal Article
• Language: English
• Published: New York Springer US 01-02-2017; Springer Nature B.V
• Subjects: Activation energy; Binary mixtures; Chemistry; Chemistry and Materials Science; Composition; Condensed Matter Physics; Geochemistry; Industrial Chemistry/Chemical Engineering; Inorganic Chemistry; Isobutanol; Molar volume; Oceanography; Physical Chemistry; Pressure; Thermal expansion; Viscosity; McAllister equation; Binary mixture; Redlich–Kister equation; Viscosity deviation; Alkanols; Excess molar volume
• ISSN: 0095-9782; 1572-8927
• DOI: 10.1007/s10953-017-0580-4

Densities,
ρ
, and viscosities,
η
, of pure isobutanol, 1-amino-2-propanol, and 1-propanol, along with their binary mixtures of {
x
1
isobutanol + 
x
2
1-propanol}, {
x
1
1-amino-2-propanol + 
x
2
1-propanol}, and {
x
1
1-amino-2-propanol + 
x
2
isobutanol} were measured over the entire composition range and at temperatures (293.15–333.15) K at ambient pressure (81.5 kPa). Excess molar properties such as the excess molar volume,
V
m
E
, partial molar volumes,
V
¯
1
and
V
¯
2
, excess partial molar volumes,
V
¯
1
E
and
V
¯
2
E
, thermal expansion coefficient,
α
, excess thermal expansion coefficient,
α
E
, viscosity deviation, Δ
η
, and the excess Gibbs energy of activation, ∆
G
E*
, for the binary mixtures were calculated from the experimental values of densities and viscosities. The excess values of the binary mixtures are negative in the entire composition range and at all temperatures, and increase with increasing temperature. Viscosity deviations, Δ
η
, are negative over the entire composition range and decrease with increasing temperature. The viscosities of the mixtures were correlated by the models of McAllister, Heric, Hind, Katti, and Nissan. The obtained data were correlated by Redlich–Kister equation and the fitting parameters and standard deviations were determined.