Investigation of nanostructured TiO2 thin film coatings for DSSCs application using natural dye extracted from jabuticaba fruit as photosensitizers

• Published in: Ionics Vol. 25; no. 6; pp. 2893 - 2902
• Main Authors: Sampaio, D. M., Babu, R. Suresh, Costa, H. R. M., de Barros, A. L. F.
• Format: Journal Article
• Language: English
• Published: Berlin/Heidelberg Springer Berlin Heidelberg 01-06-2019; Springer Nature B.V
• Subjects: Atomic force microscopy; Chemistry; Chemistry and Materials Science; Clean energy; Coated electrodes; Composition effects; Condensed Matter Physics; Dye-sensitized solar cells; Dyes; Efficiency; Electrochemistry; Energy sources; Energy Storage; Fourier transforms; Infrared analysis; Infrared spectroscopy; Microscopy; Morphology; Nanostructure; Optical and Electronic Materials; Original Paper; Photovoltaic cells; Renewable and Green Energy; Scanning electron microscopy; Spin coating; Thin film coatings; Thin films; Titanium dioxide; Thin films; Dye-sensitized solar cells; TiO; Natural dyes; Photovoltaics; Energy storage
• ISSN: 0947-7047; 1862-0760
• DOI: 10.1007/s11581-018-2753-6

Solar power is a renewable and promising solution to the today’s world energy needs. Recently, researchers in finding an alternative energy resource for the next generation lead to the production of efficient photovoltaic cells. Herein, dye-sensitized solar cells (DSSCs) containing semiconducting nanostructured TiO
2
thin film photoanodes were fabricated by spin-coating technique, using a self-constructed spin coater, which is a simple and cost-effective method. The composition and superficial characteristics of the films were studied by scanning electron microscopy (SEM), atomic force microscopy (AFM), and Fourier transform infrared spectroscopy (FTIR). Microscopic analysis revealed the electrode surface morphology, and microstructure were influenced by spin-coating technique compared to doctor blade method. The natural dyes of anthocyanin were extracted from jabuticaba (
Plinia cauliflora
) fruit using a simple extraction technique, used as photosensitizers in DSSCs and their characteristics were studied. The extracts showed the UV–Vis absorptions in the 450–600 nm range with broad maxima at ~ 545 nm. FTIR showed the presence of anthocyanin in the dye molecules of jabuticaba fruit, which can be related to a better photon to electron conversion. The photoelectrochemical performance and the efficiency of assembled DSSCs using jabuticaba fruit dye extract were evaluated, and efficiency enhancement was obtained by spin-coated TiO
2
electrodes. The efficiency and fill factor of the DSSC using jabuticaba fruit dye were 0.13% and 0.29%, respectively. The results successfully showed that the DSSC, using jabuticaba fruit extract as a dye photosensitizer, is valuable for the preparation of eco-friendly, less-expensive, renewable, and clean sources of energy.