The First Example of Dienediamine Utilization in the Nenitzescu Reaction

For the first time, a dienediamine – 2,4-bis(dimethylamino)-1-nitrobuta-1,3-diene – has been used in a reaction with benzoquinone to give ‘Nenitzescu’ product 2-(2-dimethylaminovinyl)-5-hydroxy-3-nitrobenzofuran together with 1,4-cycloaddition products 2,6-bis(dimethylamino)-1,4-naphthoquinone and 2...

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Bibliographic Details
Published in:Mendeleev communications Vol. 5; no. 2; pp. 68 - 69
Main Authors: Lyubchanskaya, Valeriya M., Alekseeva, Lyudmila M., Granik, Vladimir G.
Format: Journal Article
Language:English
Published: Elsevier B.V 1995
Online Access:Get full text
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Summary:For the first time, a dienediamine – 2,4-bis(dimethylamino)-1-nitrobuta-1,3-diene – has been used in a reaction with benzoquinone to give ‘Nenitzescu’ product 2-(2-dimethylaminovinyl)-5-hydroxy-3-nitrobenzofuran together with 1,4-cycloaddition products 2,6-bis(dimethylamino)-1,4-naphthoquinone and 2,6-bis(dimethylamino)-5,10-anthraquinone.
ISSN:0959-9436
DOI:10.1070/MC1995v005n02ABEH000462