Electrochemical synthesis and characterization of basic bismuth nitrate [Bi6O5(OH)3](NO3)5·2H2O: a potential highly efficient sorbent for textile reactive dye removal

• Published in: Research on chemical intermediates Vol. 46; no. 1; pp. 661 - 680
• Main Authors: Najdanović, Slobodan M., Petrović, Milica M., Kostić, Miloš M., Mitrović, Jelena Z., Bojić, Danijela V., Antonijević, Milan D., Bojić, Aleksandar Lj
• Format: Journal Article
• Language: English
• Published: Dordrecht Springer Netherlands 2020; Springer Nature B.V
• Subjects: Bismuth; Catalysis; Chemical synthesis; Chemistry; Chemistry and Materials Science; Deionization; Dyes; Electrochemical analysis; Heat treatment; Inorganic Chemistry; Isotherms; Physical Chemistry; Sorbents; Sorption; Substrates; Sorption; Basic bismuth nitrate; Textile dye; Reactive Blue 19; Electrochemical synthesis
• ISSN: 0922-6168; 1568-5675
• DOI: 10.1007/s11164-019-03983-1

A new method of synthesis was developed for the preparation of basic bismuth nitrate [Bi
6
O
5
(OH)
3
](NO
3
)
5
·2H
2
O (ECBBN). Electrochemical synthesis of the material was carried out by galvanostatic electrodeposition from an acidic Bi(III) solution on a Ti substrate and further thermal treatment in air at 200 °C. Characterization of ECBBN was conducted by employing SEM–EDX, N
2
adsorption, XRD and FTIR, and its pI was also determined. The analyses showed that the material obtained was pure [Bi
6
O
5
(OH)
3
](NO
3
)
5
·2H
2
O. Morphologically, ECBBN aggregates were composed of crystals, some smaller than 50 nm. Electrochemically synthesized sorbent (ECBBN) was used for the removal of the textile dye Reactive Blue 19 (RB19) from deionized water and model solutions of polluted river water, and it showed considerably superior sorption performance compared to other inorganic sorbents synthesized by conventional methods reported in the literature. A kinetic study suggests that the sorption process is both under reaction and diffusion control. Equilibration of the sorption process was attained in several minutes, i.e. the sorption process is very fast. The sorption equilibrium data were well interpreted by the Langmuir, Redlich–Peterson and Brouers–Sotolongo isotherm. Using Langmuir isotherm, the maximum sorption capacity of ECBBN was reached at pH 2 and was 1049.19 mg g
−1
.