Optimized Bioleaching Pre-treatment of UG-2 PGM Flotation Concentrate Using Design of Experiments

• Published in: Journal of sustainable metallurgy Vol. 10; no. 2; pp. 525 - 541
• Main Authors: Shemi, A., Chipise, L., Yah, C. S., Kumar, A., Moodley, S., Rumbold, K., Simate, G., Ndlovu, S.
• Format: Journal Article
• Language: English
• Published: Cham Springer International Publishing 2024; Springer Nature B.V
• Subjects: Archaea; Bacterial leaching; Base metal; Biological activity; Bioprocessing; Copper; Correlation coefficients; Design of experiments; Earth and Environmental Science; Environment; Flotation; Hydrometallurgy; Inoculum; Investigations; Metallic Materials; Metals; Nickel; Platinum metals; Research Article; Sustainable Development; Base metals; Thermophilic bacteria; PGMs; Bioleaching; Optimization
• ISSN: 2199-3823; 2199-3831
• DOI: 10.1007/s40831-024-00800-x

The depletion of the Merensky ore has led the South African platinum industry into largely mining and processing Upper Group Two (UG-2) ore for the extraction of Platinum Group Metals (PGMs). However, the processing of the UG-2 material is not fully amenable to the conventional pyrometallurgical route due to the high chrome content. Therefore, in this study, a bio-based process for base metal extraction from UG-2 flotation concentrates was investigated. This study represents only part of the work done in a broader investigation to develop a completely biological two-stage process for the extraction of base metals and PGEs. In this paper, only the first stage of the process is presented. This study evaluated a mixture of indigenous thermoacidophile archaebacteria namely,
Acidianus brierleyi, Sulfolobus sp.
, and
Metallosphaera sedula
. A statistical Design of Experiments (DOE) was used for finding optimal conditions. Factors investigated included particle size, pH, pulp density, inoculum dosage, and temperature. Optimal extraction efficiencies of 92% for Co, 97% for Cu, and 99% for Ni were predicted at correlation coefficients of 92.5%, 93.2%, and 88.0%, respectively, thus, verifying the fitness of the model. Optimal base metal extractions obtained were 99.3% for Co, 90.1% for Cu, 41.58% for Fe, and 99.5% for Ni. The results showed a substantial extraction of base metals from UG-2 PGM flotation concentrate suggesting a potentially feasible option for industrial bioprocessing of PGM concentrates. To the best of the authors’ knowledge, this is the first report on bioleaching of base metals from UG-2 flotation concentrates.
Graphical Abstract