Nitrodeiodination of Polyiodopyrazoles: a Convenient Synthesis of 4-Nitroiodopyrazoles

A number of 3,4-, 4,5-diiodo- and 3,4,5-triiodo-1-methylpyrazoles 2a–f have been converted into the corresponding almost inaccessible 3-, 5-iodo- and 3,5-diiodo-1-methyl-4-nitropyrazoles 3a–f by nitration with an HNO3–H2SO4 mixture.

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Bibliographic Details
Published in:Mendeleev communications Vol. 5; no. 6; pp. 233 - 234
Main Authors: Tretyakov, Eugene V., Vasilevsky, Sergei F.
Format: Journal Article
Language:English
Published: Elsevier B.V 1995
Online Access:Get full text
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Description
Summary:A number of 3,4-, 4,5-diiodo- and 3,4,5-triiodo-1-methylpyrazoles 2a–f have been converted into the corresponding almost inaccessible 3-, 5-iodo- and 3,5-diiodo-1-methyl-4-nitropyrazoles 3a–f by nitration with an HNO3–H2SO4 mixture.
ISSN:0959-9436
DOI:10.1070/MC1995v005n06ABEH000542