Evolution of precursor powders prepared by oxalate freeze drying towards high performance Bi-2212 wires

• Published in: Ceramics international Vol. 47; no. 3; pp. 3299 - 3305
• Main Authors: Jin, L.H., Liu, G.Q., Xu, X.Y., Jiao, G.F., Zheng, H.L., Hao, Q.B., Zhang, S.N., Li, C.S., Zhang, P.X.
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 01-02-2021
• Subjects: Bi-2212 wire; Microstructure; Phase evolution; Precursor powder; Precursor powder; Phase evolution; Microstructure; Bi-2212 wire
• ISSN: 0272-8842; 1873-3956
• DOI: 10.1016/j.ceramint.2020.09.170

Bi2Sr2CaCu2Ox (Bi-2212) precursor powders were synthesized by the oxalate freeze drying (OFD) method. In comparison with the traditional method, the novel method could shorten the processing steps and thus improve the fabrication efficiency of precursor powder. The phase, microstructure and superconducting properties of Bi-2212 precursor powders and wires were characterized by X-ray diffraction, scanning electron microscopy and four-probe method, respectively. The thermal behavior, surface area and particle size of powders were also discussed. The results indicated that large surface area and small particle size might improve the reactivity and uniformity of powders. These properties were beneficial for the rapid and homogeneous formation of Bi-2212. High-purity crystallized Bi-2212 powders without Bi-2201 and alkaline-earth cuprates phases could be achieved. Furthermore, multi-filamentary Bi-2212 wires with OFD powders showed good microstructures without noticeable pores and large secondary particles. Therefore, high engineering critical current densities (Je) of 1619 A/mm2 and critical current densities (Jc) of 7039 A/mm2 were obtained in Bi-2212 wires at 4.2K, self field. It indicated that the oxalate freeze drying method would be a potential candidate for the mass production of high performance Bi-2212 wires.