Photocatalytic TiO2 coatings on limestone

• Published in: Journal of sol-gel science and technology Vol. 60; no. 3; pp. 437 - 444
• Main Authors: Licciulli, A., Calia, A., Lettieri, M., Diso, D., Masieri, M., Franza, S., Amadelli, R., Casarano, G.
• Format: Journal Article
• Language: English
• Published: Boston Springer US 01-12-2011; Springer Nature B.V
• Subjects: Anatase; Calcite; Capillarity; Catalytic activity; Ceramics; Chemistry and Materials Science; Coatings; Colloiding; Composites; Glass; Inorganic Chemistry; Limestone; Materials Science; Nanocrystals; Nanotechnology; Natural Materials; Optical and Electronic Materials; Original Paper; Photocatalysis; Protective coatings; Sol-gel processes; Sols; Stone; Surface chemistry; Titanium dioxide; Ultraviolet radiation; Water absorption; X-ray diffraction; Limestone; Cultural heritage; Self-cleaning; Synthesis; Photocatalysis TiO; Microstructure
• ISSN: 0928-0707; 1573-4846
• DOI: 10.1007/s10971-011-2574-9

The application of photocatalytic coatings on stone has been investigated for providing surface protection and self-cleaning properties. Sol–Gel and hydrothermal processes were used to synthesise TiO
2
colloidal suspensions and coatings with enhanced photocatalytic activity without any thermal curing of the coated stone. The stone was a porous limestone (apulian sedimentary carbonatic, calcite stone). Films and powders prepared from TiO
2
sols were studied using X-ray diffraction to evaluate the microstructure and identify rutile and anatase phases. A morphological and physical characterisation was carried out on coated and uncoated stone to establish the changes of appearance, colour, water absorption by capillarity and water vapour permeability. The photocatalytic activity of the coated surface was evaluated under UV irradiation through NO
x
and organics degradation tests. The performances of the synthesised TiO
2
sols were compared with commercial TiO
2
suspension. Since the coating doesn’t need temperature treatments for activating the photocatalytic properties, the nano-crystalline hydrothermal TiO
2
sols seem good candidate for coating applications on stone that cannot be annealed after the coating application.