Systematic Synthesis and Crystal Structures of Tetraaryltellurium Compounds Ar4TeIV

Systematic Synthesis and Crystal Structures of Tetraaryltellurium Compounds Ar4TeIV

Hypervalent tetraaryltellurium(IV) compounds of the type Ar4TeIV (1: Ar = C6H5; 2: Ar = p-H3CC6H4; 3: Ar = p-t-BuC6H4; 4: Ar = p-F3CC6H4) were prepared via a convenient one-pot reaction between the isolated corresponding ArLi reagent and TeCl4. X-ray crystallographic analyses of 1–4 revealed distort...

Full description

Saved in:
Bibliographic Details
Published in:Bulletin of the Chemical Society of Japan Vol. 92; no. 3; pp. 661 - 663
Main Authors: Kobayashi, Sho, Sugamata, Koh, Minoura, Mao
Format: Journal Article
Language:English
Published: Tokyo The Chemical Society of Japan 15-03-2019
Chemical Society of Japan
Subjects:
Crystal structure
Crystallography
Crystals
Dihedral angle
Reagents
Hypervalent
Tellurium
Berry pseudorotation
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Hypervalent tetraaryltellurium(IV) compounds of the type Ar4TeIV (1: Ar = C6H5; 2: Ar = p-H3CC6H4; 3: Ar = p-t-BuC6H4; 4: Ar = p-F3CC6H4) were prepared via a convenient one-pot reaction between the isolated corresponding ArLi reagent and TeCl4. X-ray crystallographic analyses of 1–4 revealed distorted pseudo-trigonal-bipyramidal (TBP) structures for Ar4Te and the TBP character was analyzed by the dihedral angle method.
ISSN:0009-2673
1348-0634
DOI:10.1246/bcsj.20180380