Durability and wettability of varnishes on the modified and aged surfaces of short rotation teak wood

• Published in: Pigment & resin technology Vol. 53; no. 4; pp. 464 - 474
• Main Authors: Basri, Efrida, Martha, Resa, Damayanti, Ratih, Rahayu, Istie, Darmawan, Wayan, Gérardin, Philippe
• Format: Journal Article
• Language: English
• Published: Bradford Emerald Publishing Limited 20-05-2024; Emerald Group Publishing Limited
• Subjects: Atmospheric pressure; Contact angle; Durability; Fourier transforms; Free energy; Furfuryl alcohol; Gluing; Glycerol; Liquids; Maleic anhydride; Protective coatings; Sessile drop method; Solvents; Surface properties; Surface roughness; Temperature; Varnishes; Water quality; Wettability; Acrylic and alkyd varnish; Wettability; Surface roughness; Thermal and chemical modification; Surface free energy; Bonding quality
• ISSN: 0369-9420; 0369-9420; 1758-6941
• DOI: 10.1108/PRT-09-2022-0110

Purpose
The surface characteristics of thermally and chemically modified wood, such as surface roughness, surface free energy (SFE) and wettability, are important properties that influence further manufacturing processes such as gluing and coating. The aim of this paper was to determine the influence of the surface roughness of thermally and chemically modified teak wood on their SFE, wettability and bonding quality for water-based acrylic and solvent-based alkyd varnishes. In addition, durability against subterranean termites in the field of these modified teak woods was also investigated to give a valuable information for their further application.
Design/methodology/approach
The woods tested in this study were fast-growing teak woods that were prepared in untreated and treated with furfuryl alcohol (FA), glycerol maleic anhydride (GMA) and thermal. SFE values were calculated using the Rabel method. The wettability values were measured based on the contact angle between varnish liquids and wood surfaces using the sessile drop method, and the Shi and Gardner model model was used to evaluate the wettability of the varnishes on the wood surface. The bonding quality of the varnishes was measured using a cross-cut test based on ASTM 3359-17 standard. In addition, durability against subterranean termites in the field of these modified teak woods was also investigated according to ASTM D 1758-06.
Findings
The results showed that furfurylated and GMA-thermal 220°C improved the durability of teak wood against termites. The furfurylated teak wood had the roughest surface with an arithmetic average roughness (Ra) value of 15.65 µm before aging and 27.11 µm after aging. The GMA-thermal 220°C treated teak wood was the smoothest surface with Ra value of 6.44 µm before aging and 13.75 µm after aging. Untreated teak wood had the highest SFE value of 46.90 and 57.37 mJ/m2 before and after aging, respectively. The K values of untreated and treated teak wood increased owing to the aging treatment. The K values for the water-based acrylic varnish were lower than that of the solvent-based alkyd varnish. The untreated teak wood with the highest SFE produced the highest bonding quality (grades 4–5) for both acrylic and alkyd varnishes. The solvent-based alkyd varnish was more wettable and generated better bonding quality than the water-based acrylic varnish.
Originality/value
The originality of this research work is that it provides evaluation values of the durability and SFE. The SFE value can be used to quantitatively determine the wettability of paint liquids on the surface of wood and its varnish bonding quality.