Viscosity database for ternary Cu–Cr–X (X=Ni, Si, Zr) alloys based on CALPHAD-type modeling

• Published in: Calphad Vol. 83; p. 102623
• Main Authors: Shi, Yuchao, Hu, Biao, Zhou, Jiaqiang, Chen, Jinlin, Wang, Yufei, Lan, Xinyue, Wang, Qingping, Du, Yong
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 01-12-2023
• Subjects: CALPHAD; Liquid alloys; Thermophysical properties; Viscosity model; CALPHAD; Liquid alloys; Thermophysical properties; Viscosity model
• ISSN: 0364-5916; 1873-2984
• DOI: 10.1016/j.calphad.2023.102623

A viscosity model with composition and temperature dependence for the liquid alloys of the Cu–Cr–X (X = Ni, Si, Zr) systems was developed using the CALPHAD (CALculation of PHAse Diagrams) approach. Based on the critical review of the available experimental data for pure metal viscosity, the viscosities of pure liquid Cu, Cr, Zr, Ni and Si were simulated with the Arrhenius formula. The viscosities of the binary liquid alloys of the Cu–Ni, Cu–Si, Cu–Zr, Cr–Ni, Cr–Si and Ni–Zr systems at different temperatures were evaluated using the CALPHAD-type formalism. The non-linear viscosity behavior resulting from chemical short-range order was described using temperature-dependent binary interaction parameters. The viscosities of the Cu–Cr and Cr–Zr liquid alloys were predicted employing the Hirai equation. The viscosities of the Cu–Cr–Zr, Cu–Cr–Ni and Cu–Cr–Si ternary liquids were directly extrapolated using the Redlish-Kister-Muggianu equation from the parameters of the binary systems. A comprehensive understanding of the temperature-composition-solidification phase-viscosity relationship was established for ternary melts. The satisfactory agreement observed between calculations and experimental data validates the use of CALPHAD-type viscosity modeling, supporting the suitability of the constructed viscosity database for predicting the viscosity of high-performance Cu-based alloys.
•The viscosities of pure liquid Cu, Cr, Zr, Ni and Si were simulated using the Arrhenius formula.•The viscosities of binary liquid alloys were evaluated using a CALPHAD-type model.•A relationship of temperature-composition-phase-viscosity for the Cu–Cr–X (X = Ni, Si, Zr) systems was constructed.