A novel concept of symmetry in the model of fluctuational thermodynamics

A novel concept of symmetry in the model of fluctuational thermodynamics

An exact solution of the van der Waals-Maxwell problem proposed by Gibbs in the parametric form is considered as a possible model for the reliable and consistent description of the coexistence curves in real fluids: Ar, C 2H 4, CO 2, H 2O from triple and up to the critical points. A simple rescaling...

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Bibliographic Details
Published in:Journal of molecular liquids Vol. 105; no. 2; pp. 165 - 177
Main Authors: Mazur, V.A., Rogankov, V.B.
Format: Journal Article
Language:English
Published: Elsevier B.V 30-04-2003
Online Access:Get full text
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Summary:An exact solution of the van der Waals-Maxwell problem proposed by Gibbs in the parametric form is considered as a possible model for the reliable and consistent description of the coexistence curves in real fluids: Ar, C 2H 4, CO 2, H 2O from triple and up to the critical points. A simple rescaling procedure of the Gibbs parameter maps the van der Waals-Maxwell results into the phase diagram of real fluid.
ISSN:0167-7322
1873-3166
DOI:10.1016/S0167-7322(03)00048-5