A modified palladium catalysed reductive amination procedure

New, extended applications of a modified palladium catalysed reductive amination procedure are described; a mechanistic hypothesis alternative to the common imine pathway is proposed. This versatile method advances the usual reductive amination processes in terms of yield and shows high stereoselect...

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Bibliographic Details
Published in:	Tetrahedron Vol. 58; no. 28; pp. 5669 - 5674
Main Authors:	Berdini, Valerio, Cesta, Maria C, Curti, Roberto, D'Anniballe, Gaetano, Bello, Nicoletta Di, Nano, Giuseppe, Nicolini, Luca, Topai, Alessandra, Allegretti, Marcello
Format:	Journal Article
Language:	English
Published:	Elsevier Ltd 2002
Subjects:	3- endo-tropanamine ammonium formate hemiaminal palladium catalysis reductive amination tropanone palladium catalysis reductive amination ammonium formate 3- endo-tropanamine hemiaminal tropanone
Online Access:	Get full text
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Summary:	New, extended applications of a modified palladium catalysed reductive amination procedure are described; a mechanistic hypothesis alternative to the common imine pathway is proposed. This versatile method advances the usual reductive amination processes in terms of yield and shows high stereoselectivity whether applied to constrained carbonyl compounds. New, extended applications of a modified palladium catalysed reductive amination procedure are described; a mechanistic hypothesis alternative to the common imine pathway is proposed.
ISSN:	0040-4020 1464-5416
DOI:	10.1016/S0040-4020(02)00530-6