Diaquabis(4,4′-bipyridine-κ N )bis(2,4,5-trifluoro-3-hydroxybenzoato-κ O 1 )manganese(II)
In the title compound, [Mn(C7H2F3O3)2(C10H8N2)2(H2O)2], the MnII ion, situated on a centre of inversion, has a distorted octahedral coordination geometry and is coordinated by two N atoms from two 4,4′-bipyridine ligands, two O atoms from two 2,4,5-trifluoro-3-hydroxybenzoate ligands and t...
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| Published in: | Acta crystallographica. Section E, Structure reports online Vol. 67; no. 12; p. m1826 |
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| Main Authors: | , |
| Format: | Journal Article |
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International Union of Crystallography
01-12-2011
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| Abstract | In the title compound, [Mn(C7H2F3O3)2(C10H8N2)2(H2O)2], the MnII ion, situated on a centre of inversion, has a distorted octahedral coordination geometry and is coordinated by two N atoms from two 4,4′-bipyridine ligands, two O atoms from two 2,4,5-trifluoro-3-hydroxybenzoate ligands and two water molecules. Intermolecular O—H...N hydrogen bonds link the molecules into a chain along the a axis. Interactions between neighboring chains occur through O—H...O hydrogen bonds, which link the chains into a two-dimensional supramolecular network parallel to the ac plane. In addition, O—H...O hydrogen bonds between the water molecules and carboxylate groups also exist in the the crystal structure. |
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| AbstractList | In the title compound, [Mn(C7H2F3O3)2(C10H8N2)2(H2O)2], the MnII ion, situated on a centre of inversion, has a distorted octahedral coordination geometry and is coordinated by two N atoms from two 4,4′-bipyridine ligands, two O atoms from two 2,4,5-trifluoro-3-hydroxybenzoate ligands and two water molecules. Intermolecular O—H...N hydrogen bonds link the molecules into a chain along the a axis. Interactions between neighboring chains occur through O—H...O hydrogen bonds, which link the chains into a two-dimensional supramolecular network parallel to the ac plane. In addition, O—H...O hydrogen bonds between the water molecules and carboxylate groups also exist in the the crystal structure. |
| Author | Yang, Xi-Kun Min, Chun-Gang |
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| Cites_doi | 10.1002/hc.520030422 10.1107/S0108767307043930 10.1007/s11224-010-9712-9 10.1107/S1600536809027445 |
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| References | Sheldrick (rn2092_bb4) 2008; 64 Ma (rn2092_bb3) 2006; 691 Shi (rn2092_bb5) 2011; 22 Gielen (rn2092_bb2) 1992; 3 rn2092_bb1 Zhu (rn2092_bb6) 2009; 65 |
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| Snippet | In the title compound, [Mn(C7H2F3O3)2(C10H8N2)2(H2O)2], the MnII ion, situated on a centre of inversion, has a distorted octahedral coordination geometry and... |
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| Title | Diaquabis(4,4′-bipyridine-κ N )bis(2,4,5-trifluoro-3-hydroxybenzoato-κ O 1 )manganese(II) |
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